Statistical Product Selectivity Modeling and Optimization for γ-Al2O3-Supported Cobalt Catalysts-Based Fischer–Tropsch Synthesis

The statistical selectivity models were developed for four different Fischer–Tropsch synthesis product range, including methane (CH₄), light olefins (C₂=C₄), light paraffins (C₂–C₄), and long-chain hydrocarbons (C₅₊), based on the experimental data obtained over thirteen γ-Al₂O₃ supported cobalt-based catalysts with different cobalt particle and pore sizes. The input variables consist of cobalt metal particle size and catalyst pore size. The cubic and quadratic polynomial equations were fitted to the experimental data, however, the mathematical models were subjected to model reduction for the enhancement of model adequacy, which was investigated through ANOVA. The multi-objective optimization revealed that the maximum C₅₊?selectivity (84.150%) could be achieved at the cobalt particle size and pore sizes of 14.764 and 23.129 nm, respectively, while keeping the selectivity to other hydrocarbon products minimum.

Graphic Abstract

     

Socially Assistive Robots in Elderly Care: A Mixed-Method Systematic Literature Review

The world’s population is aging, and developed countries are engaged in developing a new aged-care paradigm to reduce spiraling healthcare costs. Assistive technologies like Socially Assistive Robots (SAR) are being considered as enablers to support the process of care giving or keep elderly at home longer. This article reports a mixed-method systematic review of SAR in elderly care and recognizes its impact on elderly well-being, integrating evidence from qualitative and quantitative studies. It follows the principles explained in Cochrane Handbook for Systematic Reviews of Interventions and classifies interventions, measures, and outcomes of field trials of SAR in elderly care. Eighty-six studies in 37 study groups have been included. The findings imply positive effects of SAR on elderly well-being. Ten significant recommendations are made to help avoid the current limitations of existing research and to improve future research and its applicability. This review revealed that SAR can potentially enhance elderly well-being and decrease the workload on caregivers. There is a need for rigorous research methodology, person-centered care, caregiver expectation model, multimodal interaction, multimodal data collection, and modeling of culturally diverse groups to facilitate acceptability of SAR.     

Fault detection for continuous‐time switched systems under asynchronous switching

In this paper, the problem of fault detection for continuous‐time switched systems under asynchronous switching is investigated. The designed fault detection filter is assumed to be asynchronous with the original systems. Attention is focused on designing a fault detection filter such that the estimation error between the residual and the fault is minimized in the sense of H _∞ norm. By employing piecewise Lyapunov function and average dwell time techniques, a sufficient condition for the existence of such a filter is exploited in terms of certain linear matrix inequalities. Finally, an example of a switched electrical circuit is provided to illustrate the effectiveness of the proposed approach. Copyright © 2013 John Wiley & Sons, Ltd.     

Synthesis of novel polyimides containing side‐chain azo‐2‐naphthol moieties

An amine‐ester derivative of isoeugenol was prepared in three steps. This amine‐ester was converted to diazonium salt and subsequently was reacted with 2‐naphthol and a novel isoeugenol ester‐azo derivative as a new monomer was obtained in quantitative yield. This monomer was characterized by high‐field ¹H‐NMR, IR, and elemental analysis and then was used for the preparation of model compound and polymerization reactions. 4‐Phenyl‐1,2,4‐triazoline‐3,5‐dione was allowed to react with this new monomer. The reaction was very fast and gave only one double adduct by Diels–Alder and ene pathways in excellent yield. The polymerization reactions of novel monomer with bistriazolinediones [bis(p‐3,5‐dioxo‐1,2,4‐triazolin‐4‐ylphenyl)methane and 1,6‐bis(3,5‐dioxo‐1,2,4‐triazolin‐4‐yl)hexane] were carried out in N,N‐dimethylacetamide at room temperature. The reactions were exothermic, fast, and gave novel heterocyclic polyimides by repetitive Diels–Alder‐ene polyaddition reactions. Some structural characterization and physical properties of these novel heterocyclic polyimides are reported. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 1942–1951, 2003     

Serendipity in Recommender Systems: A Systematic Literature Review

A recommender system is employed to accurately recommend items,which are expected to attract the user's attention.The over-emphasis on the accuracy of the recommendations can cause information over-specialization and make recommendations boring and even predictable.Novelty and diversity are two partly useful solutions to these problems.However,novel and diverse recommendations cannot merely ensure that users are attracted since such recommendations may not be relevant to the user's interests.Hence,it is necessary to consider other criteria,such as unexpectedness and relevance.Serendipity is a criterion for making appealing and useful recommendations.The usefulness of serendipitous recommendations is the main superiority of this criterion over novelty and diversity.The bulk of studies of recommender systems have focused on serendipity in recent years.Thus,a systematic literature review is conducted in this paper on previous studies of serendipity-oriented recommender systems.Accordingly,this paper focuses on the contextual convergence of serendipity definitions,datasets,serendipitous recommendation methods,and their evaluation techniques.Finally,the trends and existing potentials of the serendipity-oriented recommender systems are discussed for future studies.The results of the systematic literature review present that the quality and the quantity of articles in the serendipity-oriented recommender systems are progressing.     

Process Mining Approach of a New Water Quality Index for Long-Term Assessment under Uncertainty Using Consensus-Based Fuzzy Decision Support System

One of the biggest challenges in water quality monitoring is how to optimize big Data gathered from a wide range of resources. This paper presented a new software-based pathway of process mining approach for extending a flexible WQI (Water Quality Index) that would deal with uncertainties derived from missing data occurrence in short- and long-term assessments. The methodology is based on integration of four multi-criteria group decision-making models coupled with fuzzy simulation including AHP (Analytical Hierarchy Process), fuzzy OWA (Ordered Weighting Average), TOPSIS (Technique for Order Preference by Similarity to Ideal Solution), and fuzzy TOPSIS that were used for data mining and group consensus evaluation.. Examining the methodology on groundwater resources being supplied for drinking in Shiraz, Iran showed high integrity, accuracy, and proximity-to-real interpretation of water quality. This was the first study where decision-making risks such as Decision Makers’ risk-prone or risk-aversion attitudes (optimistic degree), DMs’ power, and consensus degree of each water quality parameter have been considered in WQI research. The proposed index offered a flexible choice in defining the intended project duration, stakeholders’ judgments, types of water use and water resource, standards, as well as type and number of water quality parameters. Thus, beside sustaining the unity in structure, this methodology could be suggested as a potentially WQI for other regions. The presented methodology would help more efficient monitoring of water resources for drinking purpose with respect to water quality.

     

Selective harmonic elimination method for wide range of modulation indexes in multilevel inverters using ICA

Selective harmonic elimination（SHE） in multilevel inverters is an intricate optimization problem that involves a set of nonlinear transcendental equations which have multiple local minima. A new advanced objective function with proper weighting is proposed and also its efficiency is compared with the objective function which is more similar to the proposed one. To enhance the ability of the SHE in eliminating high number of selected harmonics, at each level of the output voltage, one slot is created. The SHE problem is solved by imperialist competitive algorithm（ICA）. The conventional SHE methods cannot eliminate the selected harmonics and satisfy the fundamental component in some ranges of modulation indexes. So, to surmount the SHE defect, a DC-DC converter is applied. Theoretical results are substantiated by simulations and experimental results for a 9-level multilevel inverter. The obtained results illustrate that the proposed method successfully minimizes a large number of identified harmonics which consequences very low total harmonic distortion of output voltage.     

Thermal antioxidative kinetics of sesamol in triacylglycerols and fatty acid methyl esters of sesame,olive, and canola oils

Oxidation kinetics of the triacylglycerols (TAGs) and fatty acid methyl esters (FAMEs) of sesame, olive, and canola oils were studied in the presence of the different concentrations of sesamol (0.1%–0.16%) at 60, 80, and 100°C. Sesamol increased the temperature coefficient, T_C, and Q₁₀ number of the TAGs more significantly compared to the FAMEs. All the sesamol-added TAG and FAME systems, respectively, of the olive, canola, and sesame oils, respectively, exerted increased values of the Arrhenius (activation energy, E_a, and frequency factor, A) and Eyring (enthalpy, ΔH⁺⁺, and entropy, ΔS⁺⁺) equation parameters. Sesamol improved the Gibbs free energy (ΔG⁺⁺) of the activated complex formation in the canola, sesame, and olive systems, respectively, and the effect was greater in the FAMEs.     

Preparation and characterization of poly(vinyl alcohol)/gum tragacanth/cellulose nanocomposite film

The effects of gum tragacanth obtained from two species of Astragalus Gossypinus (GT-G) and A. Parrowianus (GT-P) at two levels of 10% and 30% combined with cellulose nanofibers (CNF; 5%) on the physico-mechanical and structural properties of polyvinyl alcohol (PVA) nanocomposite film were investigated in this study. The water solubility and water vapor permeability of the films decreased with increasing the content of both gums, especially in the film containing 30% GT-P. The highest values of the tensile strength (39.3 MPa) and elongation at break (445%) belonged to the treatment containing 10% GT-P (90/10P/0). The FTIR and DSC analyses confirmed good interactions between GT and PVA in the 90/10P/0 treatment. SEM images indicated the dense structure of this film as the optimum treatment. Although the presence of CNF in the films containing GT-G improved some properties, especially the Young modulus, it impaired all the functional properties of nanocomposite GT-P film.